How do I make several speaker configurations active, like it was in 9.5?

This is how it was in 9.5:
Created few different configurations with different gains, so i could switch between different gains on the fly.

This is how it looks in 10:
Only one is available. Is this how it is supposed to be? Do i need to change something in audio connection, or am I limited because I am on Windows 7?

See this and refer to the manual: