Yes, in principle it should work absolutely fine, provided your sample library provides a means of changing the vibrato without re-striking the note. The playing technique can of course be hidden by way of the Hidden property.
As long as the instrument you’re using has been assigned with an expression map, and that expression map uses that CC, you will find you can edit it manually in the key editor or in the bottom panel of play mode… Can you be more specific (if you want to receive a specific help)?